Preheat the oven to 350 degrees F and line an 8 x 8-inch square baking pan with parchment.
Dissolve the espresso powder in hot water and set aside.
In a large bowl, whisk together the sugar, flour, cocoa, baking powder, baking soda and salt.
Whisk in the egg, milk, oil, espresso mixture, and vanilla until smooth. Fold in the chocolate chips, then transfer the batter with a spatula into the prepared pan.
Bake 30 to 35 minutes, or until a toothpick inserted in the middle comes out clean. Let cool in the pan for 15 minutes before cutting and serving.